01 - Preheat oven to 350°F. Line an 8×8-inch baking pan with parchment paper, leaving a 2-inch overhang on two sides for easy removal.
02 - Place the unsalted butter and chopped dark chocolate in a heatproof bowl. Set over a pot of barely simmering water (double boiler method) and stir gently until completely melted and smooth. Alternatively, melt in the microwave in 30-second intervals, stirring between each. Let the mixture cool for about 5 minutes.
03 - Add the granulated sugar and light brown sugar to the melted chocolate mixture. Whisk vigorously until the surface becomes glossy and well blended. Add the eggs one at a time, whisking thoroughly after each addition until fully incorporated. Stir in the vanilla extract.
04 - Gently fold the sourdough starter into the batter using a rubber spatula, blending until no streaks remain and the starter is evenly distributed throughout.
05 - Sift the all-purpose flour, unsweetened cocoa powder, and fine sea salt together directly into the batter. Fold gently with a spatula until just combined. Stop mixing as soon as no dry pockets are visible to avoid toughening the crumb.
06 - Pour the batter into the prepared baking pan and spread it into an even layer using the spatula. Scatter the mini chocolate chips or candy-coated pieces evenly across the surface, then finish with a generous layer of rainbow sprinkles.
07 - Place the pan on the center rack and bake for 28 to 32 minutes. Test for doneness by inserting a toothpick into the center—it should come out with a few moist crumbs clinging to it, not wet batter. For a denser, fudgier texture, lean toward the shorter bake time.
08 - Remove from the oven and allow the brownies to cool completely in the pan set on a wire rack. Once fully cooled, use the parchment overhang to lift the slab out and transfer to a cutting board. Slice into 16 even squares.